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Abstract A global climate model is run in radiative‐convective equilibrium including a slab ocean with a specified ocean heat transport analogous to what is seen in the tropical Pacific. The insolation is varied to create a range of global mean equilibrium temperatures. These results are compared with experiments that do not include a specified ocean heat transport. The ocean heat transport cools the coldest Sea Surface Temperatures (SSTs) and increases the SST contrast. The warmest SSTs change much less with the addition of ocean heat transport because increased atmospheric transport moves energy away from the warm region. The ocean heat transport also increases the efficiency of cooling by outgoing longwave radiation in the subsiding region, allowing for a cooler global mean SST. At colder global mean temperatures ocean heat transport creates a high‐contrast state in which abundant low clouds play a strong role in maintaining the SST contrast. This high‐contrast state abruptly transitions to a warmer, low‐SST‐contrast state as the climate is warmed by increasing insolation. At warmer temperatures comparable to the current tropics, the low cloud response is less important than longwave emission in maintaining the SST contrast. Although ocean heat transport cools the climate, it does not much affect the sensitivity of the model climate to increasing insolation. Comparison of the model results to ERA5 reanalysis data shows that mechanisms responsible for the SST distribution and energy budget changes in this idealized model are analogous to variability that occurs over the tropical Pacific Ocean. 

The onset of quantum computing calls for secrecy schemes that can provide everlasting secrecy resistant to increased computational power of an adversary. One novel physical layer scheme proposes that an intended receiver capable of performing analog cancellation of a known key-based interference would hold a significant advantage in recovering small underlying messages versus an eavesdropper performing cancellation after analog-to-digital conversion. This advantage holds even if an eavesdropper later obtains the key and employs it in their digital cancellation. Inspired by this scheme, a flexible software-defined radio receiver design capable of maintaining analog cancellation ratios over 40 dB, reaching up to and over 50 dB, is implemented. Using analog cancellation levels from the hardware testbed, practical everlasting secrecy rates up to 2.0 bits/symbol are shown to be gained by receivers performing interference cancellation in analog rather than on a digital signal processor. 

A molecular catalyst attached to an electrode sur-face can in principle offer the advantages of both homogeneous and heterogeneous catalysis. Unfortunately, some molecular catalysts constrained to a surface lose much or all of their solution performance. In contrast, we have found that when a small molecule [2Fe–2S] catalyst is incorporated into metallopolymers of the form PDMAEMA–g–[2Fe–2S] (PDMAEMA = poly(2-dimethylamino)ethyl methacrylate) and adsorbed to the sur-face, the observed rate of hydrogen production increases to kobs > 105 s-1 per active site with lower overpotential, increased life-time, and tolerance to oxygen. Herein, the electrocatalytic performances of these metallopolymers with different length polymer chains are compared to reveal the factors that lead to this high performance. It was anticipated that smaller metallopolymers would have faster rates due to faster electron and proton transfers to more accessible active sites, but the experiments show that the rates of catalysis per active site are largely independent of the polymer size. Molecular dynamics modelling reveals that the high performance is a consequence of adsorption of these metallopolymers on the surface with natural assembly that brings the [2Fe–2S] catalytic sites into close contact with the electrode surface while maintaining exposure of the sites to protons in solution. The assembly is conducive to fast electron transfer, fast proton transfer, and a high rate of catalysis regardless of polymer size. These results offer a guide to enhancing the performance of other electrocatalysts with incorporation into a polymer that provides optimal interaction of the catalyst with the electrode and with solution. 

Abstract. Tropical cirrus clouds play a critical role in the climate system and are a major source of uncertainty in our understanding of global warming. Tropical cirrus are affected by processes spanning a wide range of spatial and temporal scales, from ice microphysics on cloud scales to mesoscale convective organization and planetary wave dynamics. This complexity makes tropical cirrus clouds notoriously difficult to model and has left many important questions stubbornly unanswered. At the same time, their multi-scale nature makes them well positioned to benefit from the rise of global, high-resolution simulations of Earth's atmosphere and a growing abundance of remotely sensed and in situ observations. Rapid progress requires coordinated efforts to take advantage of these modern computational and observational abilities. In this Opinion, we review recent progress in cirrus studies, highlight important questions that remain unanswered, and discuss promising paths forward. We find that significant progress has been made in understanding the life cycle of convectively generated ``anvil cirrus and how their macrophysical properties respond to large-scale controls. On the other hand, much work remains to be done to understand how small-scale anvil processes and the climatological anvil radiative effect may respond to global warming. Thin, in situ-formed cirrus are now known to be closely tied to the thermal structure and humidity of the tropical tropopause layer (TTL), but uncertainty at the microphysical scale remains a significant barrier to understanding how these clouds regulate the TTL moisture and temperature budgets, as well as the mixing ratio of water vapor entering the stratosphere. Model representation of ice-nucleating particles, water vapor supersaturation, and ice depositional growth continue to pose great challenges to cirrus modeling. We believe that major advances in the understanding of tropical cirrus can be made through a combination of cross-tool synthesis and cross-scale studies conducted by cross-disciplinary research teams. 

Since about 1980, the tropical Pacific has been anomalously cold, while the broader tropics have warmed. This has caused anomalous weather in midlatitudes as well as a reduction in the apparent sensitivity of the climate associated with enhanced low-cloud abundance over the cooler waters of the eastern tropical Pacific. Recent modeling work has shown that cooler temperatures over the Southern Ocean around Antarctica can lead to cooler temperatures over the eastern tropical Pacific. Here we suggest that surface wind anomalies associated with the Antarctic ozone hole can cause cooler temperatures over the Southern Ocean that extend into the tropics. We use the short-term variability of the Southern Annular Mode of zonal wind variability to show an association between surface zonal wind variations over the Southern Ocean, cooling over the Southern Ocean, and cooling in the eastern tropical Pacific. This suggests that the cooling of the eastern tropical Pacific may be associated with the onset of the Antarctic ozone hole. 

As one part of an NSF-sponsored Data Science Fellowship at Cal Poly, San Luis Obispo, a group of faculty offered a unique one-unit quarter-long seminar on the history of ideas behind the core principles of Data Science. We present an overview of this seminar, its learning objectives, and outcomes and lessons learned.